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高等有机化学 双语版PDF|Epub|txt|kindle电子书版本网盘下载
- 谢普会，徐翠莲，鲍峰玉主编 著
- 出版社： 北京：化学工业出版社
- ISBN：9787122224033
- 出版时间：2015
- 标注页数：227页
- 文件大小：37MB
- 文件页数：236页
- 主题词：有机化学－高等学校－教材
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图书目录
Chapter 1 Chemical Bonding and Molecular Structure1
1.1 Localized chemical bonding1
1.2 Dipole moments3
1.3 Inductive effects and field effects3
1.4 Delocalized chemical bonding4
1.5 Resonance structures drawn for conjugated structures6
1.6 Conjugative effect7
1.7 Hyperconjugative effect8
1.8 Steric effect10
1.9 Aromaticity and Hückel's rule11
Problems19
Vocabulary20
知识要点21
Chapter 2 Stereochemistry26
2.1 Enantiomers27
2.2 Resolution of racemates36
2.3 The stereochemistry in reaction process39
Problems47
Vocabulary48
知识要点49
Chapter 3 Mechanisms of Organic Reactions52
3.1 Types of organic reactions52
3.2 The variables of organic reactions56
3.3 How do organic reactions occur:mechanisms59
3.4 Describing a reaction:intermediates62
3.5 Methods of determining mechanisms68
Problems70
Vocabulary70
知识要点71
Chapter 4 Nucleophilic Substitution74
4.1 Mechanisms of nucleophilic substitutions75
4.2 Stereochemistry of nucleophilic substitutions76
4.3 Nucleophiles and nucleophilicity77
4.4 The factors that can influence the rates of SNl,SN2 reactions79
4.5 Neighboring-group participation effect82
Problems85
Vocabulary87
知识要点87
Chapter 5 Addition and Elimination Reactions91
5.1 Electrophilic addition reactions91
5.2 Elimination reactions96
5.3 Elimination vs substitution102
Problems102
Vocabulary104
知识要点105
Chapter 6 Reactions of Carbonyl Compounds107
6.1 The nucleophilic addition reaction mechanisms107
6.2 The nucleophilic addition reactions to the carbonyl groups107
6.3 The addition and elimination reactions111
6.4 The reactivity and stereoselectivity of nucleophilic additions112
6.5 Condensation reactions113
6.6 Reaction with ylides120
6.7 The nucleophilic substitutions of carboxylic acid and their derivatives121
Problems124
Vocabulary125
知识要点126
Chapter 7 Rearrangements129
7.1 Nucleophilic rearrangements129
7.2 Electrophilic rearrangements140
7.3 Rearrangements on aromatic rings143
Problems146
Vocabulary147
知识要点148
Chapter 8 Electrophilic and Nucleophilic Aromatic Substitutions150
8.1 Electrophilic aromatic substitution150
8.2 Specific electrophilic aromatic substitution reactions151
8.3 Directing effects of substituents158
8.4 Effects of multiple substituents on electrophilic aromatic substitution159
8.5 Nucleophilic aromatic substitution160
Problems164
Vocabulary165
知识要点166
Chapter 9 Oxidation and Reduction Reactions167
9.1 Oxidation of alkenes and alkynes167
9.2 Oxidation of alcohols169
9.3 Oxidation of aldehydes and ketones173
9.4 Oxidation of aromatic side chains and the aromatic rings175
9.5 Reduction reactions175
9.6 Other reduction reactions184
9.7 Disproportionation reactions187
Problems188
Vocabulary189
知识要点189
Chapter 10 Pericyclic Reactions193
10.1 Electrocyclic ring opening/closure reactions193
10.2 Cycloaddition reactions197
10.3 Sigmatropic rearrangements204
Problems207
Vocabulary209
知识要点209
Appendix Ⅰ 《Advanced Organic Chemistry》Final Test（1）211
Appendix Ⅱ 《Advanced Organic Chemistry》Final Test（2）216
Appendix Ⅲ 《Advanced Organic Chemistry》Final Test（3）222
参考文献227